Denisyuk T., Rachkov O., Smirnov O., Khvoshchan O., Starkov I. Research on the possibility of using electrical discharge in a liquid for processing products and wastes of titanium production

Geotech. meh. 2025, 174, 151-160

 

RESEARCH ON THE POSSIBILITY OF USING ELECTRICAL DISCHARGE IN A LIQUID FOR PROCESSING PRODUCTS AND WASTES OF TITANIUM PRODUCTION

Denisyuk T.

Rachkov O.

Smirnov O.

Khvoshchan O.

Starkov I.

M.S. Poliakov Institute of Geotechnical Mechanics of the National Academy of Sciences of Ukraine

UDC 669.295:621.373

Language: English

Abstract. The article is devoted to the issue of improving the technologies for processing titanium-containing raw materials. Today, this task is relevant, has scientific and practical significance for Ukraine, given the significant reserves of titanium ores on its territory and the strategic importance of the titanium industry. The article focuses on examining the main traditional methods of processing titanium ores and on analyzing their drawbacks, among which are high energy consumption, the need for a large amount of sulfuric acid, the formation of harmful sulfur-containing waste during processing, and the need for additional cleaning processes. As a promising alternative to existing methods, the use of an electric discharge in a liquid is proposed - a high-voltage breakdown of the liquid gap between the electrodes, as a result of which a high energy density occurs in the discharge channel for a short period of time, the pressure and temperature rise sharply, the discharge channel expands rapidly, and a pressure wave is emitted into the external environment. The advantages of using an electric discharge include: environmental safety, the absence of pollution, the possibility of adjusting processing parameters. Experimental studies of the effect of electric discharge on titanium dioxide paste and waste from titanium ore production were conducted. The results of the studies showed that under the influence of factors, the source of which is an electric discharge in a liquid, the sulfur concentration decreases: in the dioxide paste up to three times, and in waste from titanium ore production - up to 2 times. At the same time, during electric discharge processing, grinding of the primary material is observed, as evidenced by the results of the analysis of the particle size composition. The study of different modes of electric discharge action made it possible to determine the rational specific energy of impact - a further increase in the specific energy of impact does not lead to significant changes in the sulfur concentration and particle size of the products. The results obtained show the possibility and confirm the prospects of using electric discharge in a liquid for processing products of the sulfate method of obtaining titanium dioxide and waste from its production for the purpose of their desulphation.

Key words: titanium dioxide, electrical discharge technology, waste desulphation.

REFERENCES

1. Khaustov, V.K. (2024), “Markets for products from metall markets for products from metallic titanium”, Scientific bulletin of the International Association of scientists. Series: Economy, management, security, technologies, vol. 3, no. 3, pp. 49–63. https://doi.org/10.56197/2786-5827/2024-3-3-4

2. Korobka, R.V. (2025), “Ecological and economic principles of investment-innovation support of titanium dioxide production in Ukraine”, Investytsii: praktyka ta dosvid, no. 2, pp. 94–101. https://doi.org/10.32702/2306-6814.2025.2.94

3 Pushkaryova, K.K. and Tereshchenko, L.V. (2023), “Assessment of the influence of nanocarbonate additives on the self-cleaning ability of cement systems”, Budivelni materiali ta vyroby, no. 1–2, pp. 26–29. DOI 10.48076/2413-9890.2023-103-05

4. Prokipchuk, I.V., Mykytin, I.M., Bedriy, M.V. and Pidgirna, M.Ya. (2023), “Assessment of peptide adsorption on titanium dioxide by fluorescent analysis”, Mizhnarodnyi naukovyi zhurnal “Hraal nauky”, no. 29, pp. 163–165. DOI 10.36074/grail-of-science.07.07.2023.026

5. Khaustov, V.K. (2023), “Prospects for titanium dioxide production development in Ukraine”, Scientific bulletin of the International Association of scientists. Series: Economy, management, security, technologies, vol. 2, no. 4, pp. 21–32. DOI 10.56197/2786-5827/2023-2-4-2

 6. Meng, X., Li, B., Tian, H., Li, R. and Zhao, J. (2024), “Comprehensive resource treatment of titanium white waste acid by chlorination method based on mechanical separation method”, Academic Journal of Science and Technology, vol. 9, no. 1, pp. 7–12. https://doi.org/10.54097/jqy9z082

7. Vakhitov, R.A., Kalafat, K.V., Taran, N.A., Bessarabov, V.I., Raienko, H.F., Sholohon, V.I., Korotkikh, M.I. and Vakhitova, L.M., (2024), “Cellulose ethers as rheology modifiers of fire-retardant paints of the reactive type”, Technologies and engineering, vol. 3 no. 20, pp. 98–109. https://doi.org/10.30857/2786-5371.2024.3.8

 8. Ahmadi, M., Amiri, P. and Amiri, N., (2015), “Combination of TiO₂-photocatalytic process and biological oxidation for the treatment of textile wastewater”, Korean Journal of Chemical Engineering, vol. 32, no. 7, pp. 1327–1332. DOI:10.1007/s11814-014-0345-3

9. Ahmad, M.K., Aziz, A.F.A., Soon, C. F., Nafarizal, N., Kamalia, A. H. N., Masaru, S. and Murakami, K. (2016), “Rutile phased titanium dioxide (TiO₂) nanorod/nanoflower based waste water treatment device”, Technological Challenges, pp. 483–490. DOI:10.1007/978-3-319-46490-9_64

10. Dharma, H.N.C., Jaafar, J., Widiastuti, N., Matsuyama, H., Rajabsadeh, S., Othman, M.H.D., Rahman, M.A., Jafri, N.N.M., Suhaimin, N.S., Nasir, A.M. and Alias, N.H. (2022), “A Review of Titanium Dioxide (TiO2)-Based Photocatalyst for Oilfield-Produced Water Treatment”, Membranes, vol. 12 no. 3, 345. https://doi.org/10.3390/membranes12030345

11. Hakhovych, N.H., Venger, V.V. and Kushnirenko, O.M., (2023), “Prerequisites and prospects for the ukrainiantitanium industry development in the postwar period”, Scientific bulletin of the International Association of scientists. Series: Economy, management, security, technologies, vol. 2, no. 3, pp. 37–51. https://doi.org/10.56197/2786-5827/2023-2-3-3

12. Kryvytskyi, E.V. and Shamko, V.V., (1979), Perekhodnye protsessy pri vysokovoltnom razriade v vode. [Transient processes during high-voltage discharge in water], Naukova dumka, Kyiv, Ukarine.

13. Rizun, A.R., Kononov, V.Yu. and Rachkov, A.N., (2013), “Electric discharge activation as a method of non-roasting opening of sulphide raw materials”, Elektronnaya Obrabotka Materialov , vol. 49, no. 6, pp. 113–115. Режим доступу: https://eom.ifa.md/ru/journal/shortview/996

14. Rizun, A.R., Denisyuk, T.D., Golen’, Y.V., Kononov, V.Y. and Rachkov, A.N. (2011), “Electric discharge disintegration and coal desulphurization in the manufacture of water-coal fuel”, Surface Engineering and Applied Electrochemistry, vol. 47, no. 1, pp. 100–102. DOI:10.3103/s1068375511010170

15 Karshyga, Z., Ultarakova, A., Lokhova, N., Yessengaziyev, A. and Kassymzhanov, K., (2022), “Processing of titanium-magnesium production waste”, Journal of Ecological Engineering, vol. 23, no. 7, pp. 215–225. https://doi.org/10.12911/22998993/150004.

16 Otgon-Uul, E.U., Baatar, M., Nanzad, U. and Lkhamsuren, J., (2024), “Preparation of titanium dioxide (TiO₂) from waste of polymetallic ore processing via sulfurization treatment”, Indonesian Journal of Chemistry, vol. 24, no. 5, pp. 1563–1572. DOI: 10.22146/ijc.89992

17. Rizun, A.R., Holenʹ, Yu.V., Denysiuk, T.D., Rachkov, A.N. and Kononov, V.Yu. (2013), “Development and implementation of the electric discharge process of selective disintegration of tailings of beneficiation of polymetallic ores”, Nauka ta innovatsii, vol. 9, no. 2, pp. 5–9. Режим доступу: http://nbuv.gov.ua/UJRN/scinn_2013_9_2_2

18. Smirnov, A.P., Zhekul, V.G., Mel’kher, Yu.I., Taftai, E.I., Khvoshchan, O.V. and Shvets, I.S. (2018), “Experimental Investigation of the Pressure Waves Generated by an Electric Explosion in a Closed Volume of a Fluid”, Surface Engineering and Applied Electrochemistry, vol. 54, no. 5, pp. 475–480. DOI: 10.3103/S1068375518050101

 

 

About the authors

Denisyuk Tetiana, Junior researcher, Institute of Pulse Processes and Technologies of the NAS of Ukraine, Mykolaiv, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it. , ORCID 0009-0009-7551-4923

Rachkov Oleksiy, Junior researcher, Institute of Pulse Processes and Technologies of the NAS of Ukraine, Mykolaiv, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it. , ORCID 0009-0002-4940-4818

Smirnov Oleksiy, Candidate of Technical Sciences (Ph.D), Senior Researcher, Institute of Pulse Processes and Technologies of the NAS of Ukraine, Mykolaiv, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it. (Corresponding author), ORCID 0000-0002-0542-1280

Khvoshchan Oleh, Candidate of Technical Sciences (Ph.D), Senior Researcher, Institute of Pulse Processes and Technologies of the NAS of Ukraine, Mykolaiv, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it. , ORCID 0000-0002-5236-8187

Starkov Ihor, Junior researcher, Institute of Pulse Processes and Technologies of the NAS of Ukraine, Mykolaiv, Ukraine, This email address is being protected from spambots. You need JavaScript enabled to view it. Mykolaiv, Ukraine, ORCID 0000-0002-9740-3468